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Harry B. Gray was born in 1935 in Woodburn, Kentucky, USA and got a B.S. in 1957 at Western Kentucky University. He began his work in inorganic chemistry at Northwestern University, where he earned his Ph.D. in 1960 working under Fred Basolo and who also recommended Ballhausen for a postdoctoral stop. Gray received a National Science Foundation (USA) fellowship and went to Copenhagen. Ligand Field Theory in those days was getting lots of attention from inorganic chemists. After this postdoctoral year at the University of Copenhagen, he joined the chemistry faculty at Columbia University, where his main interests centered on the electronic structures and reactions of inorganic complexes. Many chemists went to visit Ballhausen in this period, e.g. Spiro who is now Prof. at Princeton. Ballhausen suggested that Gray might work on the aquo-Ni(II) spectrum. Then Gray decided to work on the electronic structures of multiply bonded units such as the vanadyl, chromyl, and molybdenyl ions. |